Amy Adams
Adams' rust lame' strapless sheath was by Gucci.
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Camilla Belle
Belle wore a grey Gucci halter gown with an embellished neckline.
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Drew Barrymore
Barrymore went her own way and donned a voluminous white and print caftan by Vivienne Westwood.
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Evan Rachel Wood and Jamie Bell
The statuesque Evan Rachel Wood, with husband Jamie Bell, looked simple and chic in a black Gucci gown.
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Fergie and Josh Duhamel
The singer arrived with her actor husband.
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James Franco
Franco, in Gucci, gave a thumbs up for the star-studded bash.
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Jane Fonda
Fonda styled a black fringe jacket with a shiny silver choker and earrings.
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Jimmy Kimmel and Molly McNearney
The late-night host walked the carpet with wife McNearney.
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Kate Beckinsale
Beckinsale's Gucci gown featured a touch of metallic in egg blue color.
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Kate Hudson
Hudson wore a pale blush Gucci gown with silver bodice embellishment.
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Leonardo DiCaprio and Martin Scorsese
DiCaprio (left) posed with his Wolf of Wall Street director, Scorsese, who was honored during the event.
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Mary J. Blige
The R&B singer donned a magenta Gucci jumpsuit with black trims from the Spring 2014 collection.
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Nicole Richie
Richie chose a sheer, beaded Dolce & Gabbana floor-length gown.
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Olivia Wilde and Jason Sudeikis
The pregnant actress, with her fiance, donned a sleek black Gucci gown.
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Psy
Psy threw up a peace sign.
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Rosie Huntington-Whiteley
The model dressed up in a Gucci Spring 2014 gown.
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Salma Hayek
Hayek stunned, as usual, in a Gucci original, featuring the much-touted cream color of the moment in a halter chiffon gown that was belted and whose bodice was sprinkled with shiny beads.
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Sting
The evening ended with a Gucci-clad Sting, introduced by the luxury house’s creative director Frida Giannini, performing a five-song set of “Message in a Bottle,” “Fields of Gold,” “Englishman in New York,” “Desert Rose” and “Every Breath You Take.”
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Susan Downey and Robert Downey Jr.
The Iron Man 3 actor escorted his producer wife, Susan.
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Will Ferrell and Viveca Paulin
The Anchorman 2 actor accompanied his wife, Viveca Paulin.
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Zoe Saldana
Saldana wore a somewhat more sedate version of the Gucci patchwork glam look — this one from spring 2014.